Bis{5-methoxy-2-[(1H-pyrrol-2-yl)methyliminomethyl]phenolato}zinc(II)
نویسندگان
چکیده
The title compound, [Zn(C(13)H(13)N(2)O(2))(2)], contains a Zn(II) centre, located on a twofold rotation axis, that is coordinated by two O atoms and two N atoms from two salicylal Schiff base mol-ecules. The crystal structure is stabilized by inter-molecular C-H⋯O hydrogen bonds.
منابع مشابه
Bis{2-[(1H-pyrrol-2-yl)methyliminomethyl]phenolato-κ2 N,O}zinc(II)
In the title compound, [Zn(C(12)H(11)N(2)O)(2)], the Zn(II) atom, lying on an inversion center, is coordinated by two O atoms and two N atoms from two salicylal Schiff base ligands in a distorted square-planar geometry. A three-dimensional network is formed by inter-molecular C-H⋯N hydrogen bonds and C-H⋯π contacts.
متن کاملBis{(E)-2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}zinc(II)
The title compound, [Zn(C(15)H(14)NO(2))(2)], contains a four-coordinate Zn atom located on a twofold rotation axis that exhibits a distorted tetra-hedral geometry by two phenolate O atoms and two azomethine N atoms of the Schiff base 2-methoxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenolate ligands.
متن کاملBis{2-methoxy-6-[tris(hydroxymethyl)methyliminomethyl]phenolato-κ3 O,N,O′}manganese(II) dimethanol solvate hemihydrate
In the title complex, [Mn(C(12)H(16)NO(5))(2)]·2CH(3)OH·0.5H(2)O, the Mn(II) atom has a distorted octa-hedral coordination geometry in which two N atoms from two 6-meth-oxy-2-[tris-(hydroxy-meth-yl)methyl-imino-meth-yl]phenolate ligands adopt a trans arrangement. The Mn-O(H) bonds (mean length 2.134 Å) are significantly longer than the Mn-O and Mn-N bonds (mean length 2.011 and 2.027 Å, respect...
متن کاملBis{2-methoxy-6-[(3-pyridyl)methyliminomethyl]phenolato}copper(II)
In the mononuclear title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) atom lies on an inversion centre and adopts a square-planar coordination geometry. The dihedral angle formed by the pyridine and benzene rings is 74.61 (5)°. Intra-molecular C-H⋯O hydrogen bonds are present. The crystal structure is stabilized by weak aromatic π-π stacking inter-actions involving neighbouring pyridine rin...
متن کاملBis{4-chloro-2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}zinc(II)
The Zn atom in the title compound, [Zn(C(17)H(14)ClN(2)O)(2)], is N,O-chelated by two deprotonated Schiff base monoanionic ligands in a tetra-hedral coordination geometry. The Zn atom lies on a special position of site symmetry 2.
متن کامل